Material Safety Data Sheet
2,5-Dimethylphenol, 99+%

ACC# 95828
Section 1 - Chemical Product and Company Identification
MSDS Name: 2,5-Dimethylphenol, 99+%
Catalog Numbers: AC116540000, AC116540050, AC116541000, AC116545000
Synonyms:
2,5-Xylenol; 1,4-Dimethyl-2-Hydroxybenzene; 1-Hydroxy-2,5-Dimethylbenzene; 2,5-Xylenol; P-Xylenol.
Company Identification:

              Acros Organics N.V.
              One Reagent Lane
              Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300

Section 2 - Composition, Information on Ingredients

CAS# Chemical Name Percent EINECS/ELINCS
95-87-4 2,5-Dimethylphenol 99+% 202-461-5

Section 3 - Hazards Identification

EMERGENCY OVERVIEW

Appearance: not available solid. Flash Point: 73 deg C.
Warning! Harmful if swallowed. Causes eye and skin irritation and possible burns. May cause respiratory and digestive tract irritation. May cause kidney damage.
Target Organs: Kidneys.


Potential Health Effects
Eye: Causes eye irritation. May cause conjunctivitis and corneal inflammation.
Skin: Causes skin irritation.
Ingestion: Harmful if swallowed. May cause irritation of the digestive tract. May cause kidney damage. Human fatalities have been reported from acute poisoning. A case of fatal xylenol ingestion by a long stay mental hospital patient is described. Clinical course was similar to that observed in other phenolic poisonings with active bowel sounds, nausea, and vomiting. Severe metabolic acidosis, hypotension, and cardiac and renal failure.
Inhalation: May cause respiratory tract irritation.
Chronic: Chronic ingestion may cause effects similar to those of acute ingestion.

Section 4 - First Aid Measures


Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid imme diately.
Skin: Get medical aid. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion: Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures


General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Dust can be an explosion hazard when exposed to heat or flame.
Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam.
Flash Point: 73 deg C ( 163.40 deg F)
Autoignition Temperature: 555 deg C ( 1,031.00 deg F)
Explosion Limits, Lower:1.40 vol %
Upper: Not available.
NFPA Rating: (estimated) Health: 2; Flammability: 1; Instability: 0

Section 6 - Accidental Release Measures


General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation.

Section 7 - Handling and Storage


Handling: Wash thoroughly after handling. Use only in a well-ventilated area. Minimize dust generation and accumulation. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Keep away from heat, sparks and flame. Do not ingest or inhale.
Storage: Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - Exposure Controls, Personal Protection


Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
Chemical Name ACGIH NIOSH OSHA - Final PELs
2,5-Dimethylphenol none listed none listed none listed

OSHA Vacated PELs: 2,5-Dimethylphenol: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - Physical and Chemical Properties


Physical State: Solid
Appearance: not available
Odor: Characteristic phenolic odor
pH: Not available.
Vapor Pressure: 10 mm Hg @91.3C
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: cP75C
Boiling Point: 212 deg C
Freezing/Melting Point:74.5 deg C
Decomposition Temperature:Not available.
Solubility: 4.6g/L
Specific Gravity/Density:.9710
Molecular Formula:C8H10O
Molecular Weight:122.17

Section 10 - Stability and Reactivity


Chemical Stability: Stable under normal temperatures and pressures.
Conditions to Avoid: Incompatible materials, dust generation, excess heat.
Incompatibilities with Other Materials: Bases - acid chlorides - acid anhydrides - oxidizing agents - corrodes steel - brass - copper - copper alloys.
Hazardous Decomposition Products: Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.

Section 11 - Toxicological Information


RTECS#:      
CAS# 95-87-4: ZE5775000
LD50/LC50:
CAS# 95-87-4:
     Oral, mouse: LD50 = 383 mg/kg;
     Oral, rabbit: LD50 = 938 mg/kg;
     Oral, rat: LD50 = 444 mg/kg;
.

Carcinogenicity:
CAS# 95-87-4: Not listed by ACGIH, IARC, NTP, or CA Prop 65.

Epidemiology: Experimental tumorigenic effects have been reported.
Teratogenicity: No information found
Reproductive Effects: No information found
Mutagenicity: No information found
Neurotoxicity: No information found
Other Studies:

Section 12 - Ecological Information


Ecotoxicity: No data available. cfr. Genium
Environmental: No information available.
Physical: No information available.
Other: No information available.

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information

US DOT Canada TDG
Shipping Name: XYLENOLS, SOLID XYLENOLS
Hazard Class: 6.1 6.1
UN Number: UN2261 UN2261
Packing Group: II II

Section 15 - Regulatory Information

US FEDERAL

TSCA
     CAS# 95-87-4 is listed on the TSCA inventory.
Health & Safety Reporting List
     None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
     None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
     None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
     None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
     None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
     None of the chemicals in this product have a TPQ.
Section 313      No chemicals are reportable under Section 313.
Clean Air Act:
     This material does not contain any hazardous air pollutants.
     This material does not contain any Class 1 Ozone depletors.
     This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
     None of the chemicals in this product are listed as Hazardous Substances under the CWA.
     None of the chemicals in this product are listed as Priority Pollutants under the CWA.
     None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
     None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
     CAS# 95-87-4 is not present on state lists from CA, PA, MN, MA, FL, or NJ.

California Prop 65

California No Significant Risk Level: None of the chemicals in this product are listed.

European/International Regulations

European Labeling in Accordance with EC Directives
Hazard Symbols:
     XN
Risk Phrases:

     R 21/22 Harmful in contact with skin and if swallowed.

Safety Phrases:

     S 2 Keep out of reach of children.
     S 45 In case of accident or if you feel unwell, seek medical advice
     immediately (show the label where possible).
     S 28A After contact with skin, wash immediately with plenty of water
     .

WGK (Water Danger/Protection)

     CAS# 95-87-4: 2
Canada - DSL/NDSL
     CAS# 95-87-4 is listed on Canada's DSL List.
Canada - WHMIS
     not available.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations.
Canadian Ingredient Disclosure List

Section 16 - Additional Information

MSDS Creation Date: 9/17/1997
Revision #4 Date: 10/03/2005

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.