Material Safety Data Sheet
2-Phenoxyethanol, 99%
ACC# 96170
Section 1 - Chemical Product and Company Identification |
MSDS Name: 2-Phenoxyethanol, 99%
Catalog Numbers:
AC130240000, AC130240010, AC130240050, AC130242500
Synonyms:
Ethylene Glycol Monophenylether;1-Hydroxy-2-Phenoxyethane;
Phenylmonoglycol Ether.
Company Identification:
Acros Organics N.V.
One Reagent Lane
Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300
Section 2 - Composition, Information on Ingredients
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CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
122-99-6 |
2-Phenoxyethanol |
99% | 204-589-7 |
Section 3 - Hazards Identification
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EMERGENCY OVERVIEW
Appearance: colorless, oily liquid.
Warning! Causes severe eye irritation. Causes skin
irritation. May cause respiratory and digestive tract irritation. May
be harmful if swallowed. May cause central nervous system depression.
May cause kidney damage.
Target Organs: Kidneys, central nervous system.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause central nervous system depression, characterized
by excitement, followed by headache, dizziness, drowsiness, and
nausea. Advanced stages may cause collapse, unconsciousness, coma
and possible death due to respiratory failure. May cause kidney
failure. May be harmful if swallowed. Lesions may appear in the
brain, lungs, liver, meninges, and heart.
Inhalation:
May cause respiratory tract irritation.
Chronic:
Chronic ingestion may cause effects similar to those of acute
ingestion.
Section 4 - First Aid Measures
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Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid. Do
NOT allow victim to rub eyes or keep eyes closed.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists. Wash clothing before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. Get medical
aid if cough or other symptoms appear. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - Fire Fighting Measures
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General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Vapors may be heavier
than air. They can spread along the ground and collect in low or
confined areas. Containers may explode when heated.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam. Use
agent most appropriate to extinguish fire. Cool containers with
flooding quantities of water until well after fire is out.
Flash Point: 130 deg C ( 266.00 deg F)
Autoignition Temperature: 430 deg C ( 806.00 deg F)
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
(estimated) Health: 0; Flammability: 1; Instability: 0
Section 6 - Accidental Release Measures
|
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Provide ventilation.
Section 7 - Handling and Storage
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Handling:
Wash thoroughly after handling. Wash hands before eating. Avoid
contact with eyes, skin, and clothing. Keep container tightly
closed. Avoid ingestion and inhalation. Use with adequate
ventilation. Wash clothing before reuse.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
Section 8 - Exposure Controls, Personal Protection
|
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
2-Phenoxyethanol
|
none listed
|
none listed
|
none listed
|
OSHA Vacated PELs:
2-Phenoxyethanol:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
Section 9 - Physical and Chemical Properties
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Physical State: Liquid
Appearance: colorless, oily
Odor: Faint aromatic odor
pH: Not available.
Vapor Pressure: < 1 mm Hg @25C
Vapor Density: 4.8
Evaporation Rate:Not available.
Viscosity: 29 mPas 20 deg C
Boiling Point: 245.2 deg C @ 760.00mm Hg
Freezing/Melting Point:11 - 13 deg C
Decomposition Temperature:Not available.
Solubility: 30 G/L WATER (20°C)
Specific Gravity/Density:1.1050g/cm3
Molecular Formula:C8H10O2
Molecular Weight:138.17
Section 10 - Stability and Reactivity
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Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents - acid chlorides - acid anhydrides.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Will not occur.
Section 11 - Toxicological Information
|
RTECS#:
CAS# 122-99-6:
KM0350000
LD50/LC50:
CAS# 122-99-6:
Draize test,
rabbit, eye: 6 mg Moderate;
Draize
test, rabbit, eye: 250 ug/24H Severe;
Draize test, rabbit, skin: 500 mg/24H
Mild;
Oral, mouse: LD50 = 933
mg/kg;
Oral, rat: LD50 = 1260
mg/kg;
Skin, rabbit: LD50 = 5
mL/kg;
Skin, rat: LD50 = 14422
mg/kg;
.
Carcinogenicity:
CAS# 122-99-6:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
No information available.
Teratogenicity:
No information available.
Reproductive Effects:
No information available.
Mutagenicity:
No information available.
Neurotoxicity:
No information available.
Other Studies:
Section 12 - Ecological Information
|
Ecotoxicity:
No data available.
Fish toxicity: LC50 (96 hr) fathead minnow 345 mg/lInvertebrate
toxicity: LC50 (5 min) Photobacterium phosphoreum 32.4 ppm Microtox
test.[The Dictionary of Substances and their Effects, 1992]
Environmental:
Terrestrial: 2-phenoxyethanol is readily biodegradable, will
evaporate slowly from surfaces. Aquatic: Readily biodegradable.
Aquatic hydrolysis, volatilization direct photolysis,
bioconcentration, and adsorption to sediment are not expected to be
important. Atmospheric: Expected to exist almost entirley in the
vapor phase in the ambient atmosphere, half-life 11.6 hr. Not
expected to bioconcentrate. biological screening study have indicated
that 2-phenoxyethanol is readily biodegradable(1). 2-Phenoxyethanol
may leach readily in
Physical:
No information found.
Other:
No information available.
Section 13 - Disposal Considerations
|
Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information
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US DOT |
Canada TDG |
Shipping Name: |
Not regulated as a hazardous material |
No information available. |
Hazard Class: |
|
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UN Number: |
|
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Packing Group: |
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Section 15 - Regulatory Information
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US FEDERAL
TSCA
CAS# 122-99-6 is listed on the TSCA inventory.
Health & Safety Reporting List
CAS# 122-99-6: Effective 7/1/83, Sunset 7/1/93
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 122-99-6: immediate, delayed.
Section 313
This material contains
2-Phenoxyethanol (listed as Glycol ethers), 99%, (CAS# 122-99-6)
which is subject to the reporting requirements of Section 313 of SARA
Title III and 40 CFR Part 373.
Clean Air Act:
CAS# 122-99-6 (listed as Glycol ethers) is listed as a hazardous air p
ollutant (HAP).
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 122-99-6 can be found on the
following state right to know lists: Pennsylvania, (listed as Glycol
ethers).
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
XN
Risk Phrases:
R 22 Harmful if swallowed.
R 36/38 Irritating to eyes and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice.
WGK (Water Danger/Protection)
CAS# 122-99-6: 1
Canada - DSL/NDSL
CAS# 122-99-6 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of D2B.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 122-99-6 is listed on the Canadian Ingredient Disclosure List.
Section 16 - Additional Information
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MSDS Creation Date: 6/16/1999
Revision #3 Date: 10/03/2005
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.