Material Safety Data Sheet
Sodium oxalate, pure
ACC# 96509
Section 1 - Chemical Product and Company Identification |
MSDS Name: Sodium oxalate, pure
Catalog Numbers:
AC207720000, AC207720050, AC207721000, AC207725000
Synonyms:
Ethanedioic acid, disodium salt; Oxalic acid, disodium salt; Disodium
oxalate; Sodium oxalate.
Company Identification:
Acros Organics N.V.
One Reagent Lane
Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300
Section 2 - Composition, Information on Ingredients
|
CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
62-76-0 | Ethanedioic acid, disodium salt |
> 99.5 | 200-550-3 |
Hazard Symbols: XN
Risk Phrases: 21/22
Section 3 - Hazards Identification
|
EMERGENCY OVERVIEW
Appearance: white solid.
May cause kidney damage. May cause severe respiratory tract
irritation with possible burns. May cause severe digestive tract
irritation with possible burns. Warning!
Hygroscopic (absorbs moisture from the air). Harmful in contact with
skin and if swallowed. May cause eye and skin irritation with
possible burns.
Target Organs: Kidneys, heart, eyes, skin,
brain, nerves, mucous membranes.
Potential Health Effects
Eye:
May cause eye irritation. May result in corneal injury.
Skin:
Harmful if absorbed through the skin. Oxalate is an irritant and may
cause dermatitis. Skin lesions begin with epithelial cracking and the
formation of slow-healing ulcers. The fingers may appear cyanotic.
Ingestion:
Ulcerations of the mouth, vomiting of blood, and rapid appearance of
shock, convulsions, twitching, tetany, and cardiovascular collapse
may occur following ingestion of oxalic acid or its soluble salts.
Systemic effects may be due to formation of calcium oxalate which is
insoluble at physiological pH and can be deposited in the brain and
kidney tubules. Resultant hypocalcemia might disturb the function of
the heart and nerves. Mean lethal dose for oxalates in adults is
estimated at 10 - 30 grams (143 - 428 mg/kg).
Inhalation:
Inhalation of oxalic acid produces irritation of the respiratory
tract, ulceration of the mucous membranes, headaches, nervousness,
cough, vomiting, emaciation, back pain (due to kidney injury), and
weakness.
Chronic:
Inhalation of oxalic acid dust or mist over a long period of time
might result in weight loss and respiratory tract inflammation. Rats
administered oxalic acid at 2.5 and 5% in the diet for 70 days
developed depressed thyroid function and weight loss. A study of
railroad car cleaners in Norway who were heavily exposed to oxalic
acid solutions and vapors revealed a 53% prevalence of urolithiasis
(the formation of urinary stones), compared to a rate of 12% among
unexposed workers from the same company.
Section 4 - First Aid Measures
|
Eyes:
In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Get medical aid immediately.
Skin:
In case of contact, immediately flush skin with plenty of water for
at least 15 minutes while removing contaminated clothing and shoes.
Get medical aid immediately. Wash clothing before reuse.
Ingestion:
If swallowed, do NOT induce vomiting. Get medical aid immediately.
If victim is fully conscious, give a cupful of water. Never give
anything by mouth to an unconscious person.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
Antidote:
Intravenous administration of calcium gluconate or calcium chloride
may be required if hypocalcemia or hypocalcemic tetany occur.
Section 5 - Fire Fighting Measures
|
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
Flash Point: Not applicable.
Autoignition Temperature: Not applicable.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
(estimated) Health: 2; Flammability: 1; Instability: 0
Section 6 - Accidental Release Measures
|
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
Section 7 - Handling and Storage
|
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Minimize dust generation and accumulation. Do not
get in eyes, on skin, or on clothing. Keep container tightly closed.
Do not ingest or inhale. Discard contaminated shoes. Use only with
adequate ventilation.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Store
protected from moisture. Oxalates slowly corrode steel.
Section 8 - Exposure Controls, Personal Protection
|
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
Ethanedioic acid, disodium salt | none listed |
none listed | none listed |
OSHA Vacated PELs:
Ethanedioic acid, disodium salt:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant a respirator's use.
Section 9 - Physical and Chemical Properties
|
Physical State: Solid
Appearance: white
Odor: none reported
pH: Neutral in solution.
Vapor Pressure: Negligible.
Vapor Density: Not applicable.
Evaporation Rate:Negligible.
Viscosity: Not available.
Boiling Point: Decomposes
Freezing/Melting Point:250-270 deg C (dec)
Decomposition Temperature:250-270 deg C
Solubility: Moderately soluble in water.
Specific Gravity/Density:2.34 (water=1)
Molecular Formula:C2O4Na2
Molecular Weight:134.00
Section 10 - Stability and Reactivity
|
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
High temperatures, dust generation, moisture, Oxalates slowly corrode
steel..
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide, sodium oxide, formic acid.
Hazardous Polymerization: Has not been reported.
Section 11 - Toxicological Information
|
RTECS#:
CAS# 62-76-0: KI1750000
LD50/LC50:
CAS# 62-76-0:
Oral, mouse: LD50 = 5094 mg/kg;
Oral, rat:
LD50 = 11160 mg/kg;
Carcinogenicity:
CAS# 62-76-0:
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Epidemiology:
A study of railroad car cleaners in Norway who were heavily
exposed to oxalic acid solutions and vapors revealed a 53
% prevalence of urolithiasis (the formation of urinary s
tones), compared to a rate of 12% among unexposed workers fr
om the same company.
Teratogenicity:
No information found.
Reproductive Effects:
Oxalic acid caused kidney damage in fetal sheep and rats and
disturbed the estrus cycle in rats. Increased sperm abnormalities
were seen in the second generation of mice administered 0.2% oxalic
acid in the drinking water.
Neurotoxicity:
No information found.
Mutagenicity:
No information found.
Other Studies:
See actual entry in RTECS for complete information.
Section 12 - Ecological Information
|
No information available.
Section 13 - Disposal Considerations
|
Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information
|
|
US DOT |
IATA |
RID/ADR |
IMO |
Canada TDG |
Shipping Name: |
TOXIC SOLIDS, ORGANIC, N.O.S. |
|
|
|
No information available. |
Hazard Class: |
6.1 |
|
|
|
|
UN Number: |
UN2811 |
|
|
|
|
Packing Group: |
II |
|
|
|
|
Section 15 - Regulatory Information
|
US FEDERAL
TSCA
CAS# 62-76-0 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
SARA
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 62-76-0: acute, chronic.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product are listed as Hazardous
Substances under the CWA.
None of the chemicals in this product are listed as Priority
Pollutants under the CWA.
None of the chemicals in this product are listed as Toxic Pollutants
under the CWA.
OSHA:
None of the chemicals in this product are considered highly hazardous
by OSHA.
STATE
CAS# 62-76-0 is not present on state lists from CA, PA, MN, MA,
FL, or NJ.
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
XN
Risk Phrases:
R 21/22 Harmful in contact with skin and if
swallowed.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 62-76-0: 1
Canada - DSL/NDSL
CAS# 62-76-0 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of D2B, D1B.
Canadian Ingredient Disclosure List
Exposure Limits
Section 16 - Additional Information
|
MSDS Creation Date: 2/02/1999
Revision #6 Date: 5/24/2001
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.