Material Safety Data Sheet
2,6-Di-Tert.-Butylphenol, 99%

ACC# 96692
Section 1 - Chemical Product and Company Identification
MSDS Name: 2,6-Di-Tert.-Butylphenol, 99%
Catalog Numbers: AC113000000, AC113000010, AC113000250
Synonyms:
2,6-Bis(Tert-Butyl) Phenol.
Company Identification:

              Acros Organics N.V.
              One Reagent Lane
              Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300

Section 2 - Composition, Information on Ingredients

CAS# Chemical Name Percent EINECS/ELINCS
128-39-22,6-Di-tert-butylphenol 99 204-884-0

Section 3 - Hazards Identification

EMERGENCY OVERVIEW

Appearance: clear light straw colored.
Warning! Causes eye and skin irritation. Causes digestive and respiratory tract irritation. May cause liver damage.
Target Organs: Liver.


Potential Health Effects
Eye: Causes eye irritation.
Skin: Causes skin irritation.
Ingestion: May cause liver damage. Causes gastrointestinal tract irritation.
Inhalation: Causes respiratory tract irritation.
Chronic: No information found.

Section 4 - First Aid Measures


Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. If irritation develo ps, get medical aid.
Skin: Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse.
Ingestion: Never give anything by mouth to an unconscious person. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Get medical aid if irritation or symptoms occur.
Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid if cough or other symptoms appear.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures


General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Containers may explode in the heat of a fire.
Extinguishing Media: In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Use agent most appropriate to extinguish fire. Cool containers with flooding quantities of water until well after fire is out.
Flash Point: 118 deg C ( 244.40 deg F)
Autoignition Temperature: Not available.
Explosion Limits, Lower:N/A
Upper: N/A
NFPA Rating: Not published.

Section 6 - Accidental Release Measures


General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation.

Section 7 - Handling and Storage


Handling: Wash thoroughly after handling. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation. Wash clothing before reuse.
Storage: Store in a cool, dry, well-ventilated area away from incompatible substances. Keep containers tightly closed.

Section 8 - Exposure Controls, Personal Protection


Engineering Controls: Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits
Chemical Name ACGIH NIOSH OSHA - Final PELs
2,6-Di-tert-butylphenol none listed none listed none listed

OSHA Vacated PELs: 2,6-Di-tert-butylphenol: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to minimize contact with skin.
Respirators: Wear a NIOSH/MSHA or European Standard EN 149 approved full-facepiece airline respirator in the positive pressure mode with emergency escape provisions.

Section 9 - Physical and Chemical Properties


Physical State: Liquid above room te
Appearance: clear light straw colored
Odor: None reported
pH: Not available.
Vapor Pressure: <1.33 Pa @ 20 C
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: 253 deg C
Freezing/Melting Point:33.50 - 36.50 deg C
Decomposition Temperature:Not available.
Solubility: Insoluble.
Specific Gravity/Density:.9100g/cm3
Molecular Formula:C14H22O
Molecular Weight:206.33

Section 10 - Stability and Reactivity


Chemical Stability: Stable under normal temperatures and pressures.
Conditions to Avoid: Incompatible materials, ignition sources, excess heat.
Incompatibilities with Other Materials: Bases - acid chlorides - acid anhydrides - oxidizing agents - steel - brass - copper, copper alloys.
Hazardous Decomposition Products: Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported.

Section 11 - Toxicological Information


RTECS#:      
CAS# 128-39-2: SK8265000
LD50/LC50:
CAS# 128-39-2:
     Dermal, guinea pig: LD50 = >10 gm/kg;
     Oral, mouse: LD50 = 800 mg/kg;
     Oral, rat: LD50 = 1320 mg/kg;
     Skin, rabbit: LD50 = >10 gm/kg;
Carcinogenicity:
CAS# 128-39-2: Not listed by ACGIH, IARC, NTP, or CA Prop 65.

Epidemiology: No information available.
Teratogenicity: No information available.
Reproductive Effects: No information available.
Mutagenicity: No information available.
Neurotoxicity: No information available.
Other Studies:

Section 12 - Ecological Information


Ecotoxicity: No data available. No information available.
Environmental: Terrestrial: Slightly mobile, volatilization major fate process. Aquatic: Adsorption, volatilization, bioconcentration and biodegradation major fate processes. Atmospheric: Remains in the vapor phase, half-life 7.8 hours. Bioconcentration important fate process in aquatic environment.
Physical: No information available.
Other: No information available.

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information

US DOT Canada TDG
Shipping Name: TOXIC SOLIDS, ORGANIC, N.O.S. TOXIC SOLID ORGANIC NOS (2,6DITERTBUTYLPHENOL)
Hazard Class: 6.1 6.1
UN Number: UN2811 UN2811
Packing Group: III III

Section 15 - Regulatory Information

US FEDERAL

TSCA
     CAS# 128-39-2 is listed on the TSCA inventory.
Health & Safety Reporting List
     CAS# 128-39-2: Effective 12/19/85, Sunset 11/9/93
Chemical Test Rules
     None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
     None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
     None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
     None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
     None of the chemicals in this product have a TPQ.
SARA Codes
     CAS # 128-39-2: acute.
Section 313      No chemicals are reportable under Section 313.
Clean Air Act:
     This material does not contain any hazardous air pollutants.
     This material does not contain any Class 1 Ozone depletors.
     This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
     None of the chemicals in this product are listed as Hazardous Substances under the CWA.
     None of the chemicals in this product are listed as Priority Pollutants under the CWA.
     None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
     None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
     CAS# 128-39-2 is not present on state lists from CA, PA, MN, MA, FL, or NJ.

California Prop 65

California No Significant Risk Level: None of the chemicals in this product are listed.

European/International Regulations

European Labeling in Accordance with EC Directives
Hazard Symbols:
     XI
Risk Phrases:

     R 36/37/38 Irritating to eyes, respiratory system and skin.

Safety Phrases:

     S 16 Keep away from sources of ignition - No smoking.
     S 24/25 Avoid contact with skin and eyes.
     S 36/37 Wear suitable protective clothing and gloves.

WGK (Water Danger/Protection)

     CAS# 128-39-2: 2
Canada - DSL/NDSL
     CAS# 128-39-2 is listed on Canada's DSL List.
Canada - WHMIS
     This product has a WHMIS classification of D1B.
Canadian Ingredient Disclosure List

Section 16 - Additional Information

MSDS Creation Date: 3/04/1998
Revision #2 Date: 3/18/2003

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.