Section 2 - Composition, Information on Ingredients

CAS#	Chemical Name	Percent	EINECS/ELINCS
7732-18-5	Water	62.7	231-791-2
7705-07-9	Titanium(III) chloride	30	231-728-9
7647-01-0	Hydrogen chloride	7.3	231-595-7

Section 3 - Hazards Identification

Appearance: purple liquid.
Danger! Corrosive. Causes eye and skin burns. May cause severe respiratory tract irritation with possible burns. May cause severe digestive tract irritation with possible burns. Air sensitive.
Target Organs: Eyes, skin, mucous membranes.


Potential Health Effects
Eye: Causes eye burns. May cause chemical conjunctivitis and corneal damage.
Skin: Causes skin burns. May cause skin rash (in milder cases), and cold and clammy skin with cyanosis or pale color.
Ingestion: May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns. May cause circulatory system failure. May cause perforation of the digestive tract. May cause systemic effects.
Inhalation: May cause severe irritation of the respiratory tract with sore throat, coughing, shortness of breath and delayed lung edema. Causes chemical burns to the respiratory tract. Aspiration may lead to pulmonary edema. May cause systemic effects.
Chronic: Effects may be delayed. Adverse reproductive effects have been reported in animals.

Section 4 - First Aid Measures

Eyes: Get medical aid immediately. Do NOT allow victim to rub eyes or keep eyes closed. Extensive irrigation with water is required (at least 30 minutes).
Skin: Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion: Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid immediately.
Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures

General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Use extinguishing media appropriate to the surrounding fire. Substance is noncombustible. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Containers may explode when heated.
Extinguishing Media: Substance is noncombustible; use agent most appropriate to extinguish surrounding fire.
Flash Point: Not applicable.
Autoignition Temperature: Not applicable.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating: (estimated) Health: ; Flammability: ; Instability:

Section 6 - Accidental Release Measures

General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation. Place under an inert atmosphere.

Section 7 - Handling and Storage

Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Keep container tightly closed. Do not get on skin or in eyes. Do not ingest or inhale. Use with adequate ventilation. Handle under an inert atmosphere. Store protected from air. Discard contaminated shoes.
Storage: Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances. Corrosives area. Do not expose to air. Store under an inert atmosphere.

Section 8 - Exposure Controls, Personal Protection

Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits

Chemical Name	ACGIH	NIOSH	OSHA - Final PELs
Water	none listed	none listed	none listed
Titanium(III) chloride	none listed	none listed	none listed
Hydrogen chloride	2 ppm Ceiling	50 ppm IDLH	5 ppm Ceiling; 7 mg/m3 Ceiling

OSHA Vacated PELs: Water: No OSHA Vacated PELs are listed for this chemical. Titanium(III) chloride: No OSHA Vacated PELs are listed for this chemical. Hydrogen chloride: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to minimize contact with skin.
Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - Physical and Chemical Properties

Physical State: Liquid
Appearance: purple
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: >1.0
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point:Not available.
Decomposition Temperature:Not available.
Solubility: Miscible with water
Specific Gravity/Density:Not available.
Molecular Formula:solution
Molecular Weight:Not available.

Section 10 - Stability and Reactivity

Chemical Stability: Stable under normal temperatures and pressures.
Conditions to Avoid: Incompatible materials, exposure to air, excess heat.
Incompatibilities with Other Materials: Air, strong oxidizing agents.
Hazardous Decomposition Products: Hydrogen chloride, hydrogen chloride, titanium/titanium oxides, hydrogen gas.
Hazardous Polymerization: Has not been reported.

Section 11 - Toxicological Information

RTECS#:      
CAS# 7732-18-5: ZC0110000      
CAS# 7705-07-9: XR1924000      
CAS# 7647-01-0: MW4025000; MW4031000
LD50/LC50:
CAS# 7732-18-5:
     Oral, rat: LD50 = >90 mL/kg;
.

CAS# 7705-07-9:
.

CAS# 7647-01-0:
     Inhalation, mouse: LC50 = 1108 ppm/1H;
     Inhalation, mouse: LC50 = 20487 mg/m3/5M;
     Inhalation, mouse: LC50 = 3940 mg/m3/30M;
     Inhalation, mouse: LC50 = 8300 mg/m3/30M;
     Inhalation, rat: LC50 = 3124 ppm/1H;
     Inhalation, rat: LC50 = 60938 mg/m3/5M;
     Inhalation, rat: LC50 = 7004 mg/m3/30M;
     Inhalation, rat: LC50 = 45000 mg/m3/5M;
     Inhalation, rat: LC50 = 8300 mg/m3/30M;
     Oral, rabbit: LD50 = 900 mg/kg;
.

Carcinogenicity:
CAS# 7732-18-5: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 7705-07-9: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 7647-01-0: Not listed by ACGIH, IARC, NTP, or CA Prop 65.

Epidemiology: Experimental reproductive effects have been reported.
Teratogenicity: Teratogenic effects have occurred in experimental animals.
Reproductive Effects: Adverse reproductive effects have occurred in experimental animals.
Mutagenicity: No information found
Neurotoxicity: No information found
Other Studies:

Section 12 - Ecological Information

Ecotoxicity: Fish: Bluegill/Sunfish: 3.6 mg/L; 48Hr; CAS# 7647-01-0: Lethal (unspecified)Fish: Bluegill/Sunfish: LC50; 96 Hr; CAS# 7647-01-0: pH 3.0-3.5 No data available.
Environmental: CAS# 7647-01-0: Rapidly hydrolyzes when exposed to water. Will exhibit extensive evaporation from soil surfaces. Upon transport through the soil, hydrochloric acid will dissolve some of the soil materials (especially those with carbonate bases) and the acid will neutralize to some degree.
Physical: No information available.
Other: No information available.

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information

	US DOT	Canada TDG
Shipping Name:	TITANIUM TRICHLORIDE MIXTURES	TITANIUM TRICHLORIDE MIXTURE
Hazard Class:	8	8
UN Number:	UN2869	UN2869
Packing Group:	II	II

Section 15 - Regulatory Information

US FEDERAL

TSCA
     CAS# 7732-18-5 is listed on the TSCA inventory.
     CAS# 7705-07-9 is listed on the TSCA inventory.
     CAS# 7647-01-0 is listed on the TSCA inventory.
Health & Safety Reporting List
     None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
     None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
     None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
     None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
     CAS# 7647-01-0: 5000 lb final RQ; 2270 kg final RQ
SARA Section 302 Extremely Hazardous Substances
     CAS# 7647-01-0: 500 lb TPQ (gas only)
SARA Codes
     CAS # 7647-01-0: immediate.
Section 313
     This material contains Hydrogen chloride (CAS# 7647-01-0, 7.3%),which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373.
Clean Air Act:
     CAS# 7647-01-0 is listed as a hazardous air pollutant (HAP).
     This material does not contain any Class 1 Ozone depletors.
     This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
CAS# 7647-01-0 is listed as a Hazardous Substance under the CWA.
     None of the chemicals in this product are listed as Priority Pollutants under the CWA.
     None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
     CAS# 7647-01-0 is considered highly hazardous by OSHA.
STATE
     CAS# 7732-18-5 is not present on state lists from CA, PA, MN, MA, FL, or NJ.
     CAS# 7705-07-9 can be found on the following state right to know lists: New Jersey.
     CAS# 7647-01-0 can be found on the following state right to know lists: California, New Jersey, Pennsylvania, Minnesota, Massachusetts.

California Prop 65

California No Significant Risk Level: None of the chemicals in this product are listed.

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
     C
Risk Phrases:
     R 34 Causes burns.

Safety Phrases:
     S 26 In case of contact with eyes, rinse immediately with plenty of
     water and seek medical advice.
     S 28 After contact with skin, wash immediately with...

WGK (Water Danger/Protection)
     CAS# 7732-18-5: No information available.
     CAS# 7705-07-9: No information available.
     CAS# 7647-01-0: 1
Canada - DSL/NDSL
     CAS# 7732-18-5 is listed on Canada's DSL List.
     CAS# 7705-07-9 is listed on Canada's DSL List.
     CAS# 7647-01-0 is listed on Canada's DSL List.
Canada - WHMIS
     not available.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
     CAS# 7705-07-9 is listed on the Canadian Ingredient Disclosure List.
     CAS# 7647-01-0 is listed on the Canadian Ingredient Disclosure List.

Section 16 - Additional Information

MSDS Creation Date: 7/02/1999
Revision #6 Date: 4/03/2008

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.