Material Safety Data Sheet
Isobutyl vinyl ether, 99.5% (gc), stabilized with 0.1% potassium hydroxide
ACC# 97765
Section 1 - Chemical Product and Company Identification |
MSDS Name: Isobutyl vinyl ether, 99.5% (gc), stabilized with 0.1% potassium
hydroxide
Catalog Numbers:
AC302670000, AC302670010, AC302670050, AC302672500
Synonyms:
1-(Ethenyloxy)-2-methylpropane
Company Identification:
Acros Organics N.V.
One Reagent Lane
Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300
Section 2 - Composition, Information on Ingredients
|
CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
109-53-5 |
Isobutyl vinyl ether |
99.5 | 203-678-8 |
1310-58-3 |
Potassium hydroxide |
<1.0 | 215-181-3 |
Section 3 - Hazards Identification
|
EMERGENCY OVERVIEW
Appearance: clear, colorless liquid. Flash Point: -9.4 deg C.
Danger! Extremely flammable liquid and vapor.
Vapor may cause flash fire. May cause eye, skin, and respiratory
tract irritation. The toxicological properties of this material have
not been fully investigated.
Target Organs: None known.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological
properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties
of this substance have not been fully investigated. Vapors may cause
dizziness or suffocation.
Chronic:
None
Section 4 - First Aid Measures
|
Eyes:
Flush eyes with plenty of water for at least 15 minutes, occasionally
lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid if irritation develops or persists. Flush skin with
plenty of soap and water.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid.
Inhalation:
Remove from exposure and move to fresh air immediately. Get medical
aid if cough or other symptoms appear.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - Fire Fighting Measures
|
General Information:
Get medical aid if cough or other symptoms appear. As in any fire,
wear a self-contained breathing apparatus in pressure-demand,
MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors
can travel to a source of ignition and flash back. Extremely
flammable liquid and vapor. Vapors may be heavier than air. They
can spread along the ground and collect in low or confined areas.
Extinguishing Media:
For small fires, use water spray, dry chemical, carbon dioxide or
chemical foam. For large fires, use water spray, fog or
alcohol-resistant foam. Do NOT use straight streams of water.
Flash Point: -9.4 deg C ( 15.08 deg F)
Autoignition Temperature: 195 deg C ( 383.00 deg F)
Explosion Limits, Lower:1.40 vol %
Upper: 7.80 vol %
NFPA Rating:
(estimated) Health: ; Flammability: ; Instability:
Section 6 - Accidental Release Measures
|
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Remove all sources of ignition.
Section 7 - Handling and Storage
|
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Ground and bond containers when transferring material. Avoid contact
with eyes, skin, and clothing. Empty containers retain product
residue, (liquid and/or vapor), and can be dangerous. Keep container
tightly closed. Keep away from heat, sparks and flame. Avoid
ingestion and inhalation. Do not pressurize, cut, weld, braze,
solder, drill, grind, or expose empty containers to heat, sparks or
open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
Section 8 - Exposure Controls, Personal Protection
|
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
Isobutyl vinyl ether
|
none listed
|
none listed
|
none listed
|
Potassium hydroxide
|
2 mg/m3 Ceiling
|
none listed
|
none listed
|
OSHA Vacated PELs:
Isobutyl vinyl ether:
No OSHA Vacated PELs are listed for this chemical.
Potassium hydroxide:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
Section 9 - Physical and Chemical Properties
|
Physical State: Liquid
Appearance: clear, colorless
Odor: Ether-like
pH: Not available.
Vapor Pressure: 89 mbar @20 deg C
Vapor Density: 3.45
Evaporation Rate:Not available.
Viscosity: 0.476 mPas 5 deg C
Boiling Point: 83 deg C @ 760.00mm Hg
Freezing/Melting Point:-112 deg C
Decomposition Temperature:Not available.
Solubility: 0.7 G/L (25°C)
Specific Gravity/Density:.7690g/cm3
Molecular Formula:C6H12O
Molecular Weight:100.0834
Section 10 - Stability and Reactivity
|
Chemical Stability:
Stability unknown.
Conditions to Avoid:
Incompatible materials, ignition sources.
Incompatibilities with Other Materials:
Isobutyl vinyl ether is incompatible with strong oxidizing agents,
and strong acids. Potassium hydroxide is incompatible with acids,
amoonia hexachloroplatinate, p-Bis(1,3-dibromoethyl) benzene,
bromoform, cyclic polyethylene oxides, chlorine dioxide,
cyclopentadiene, germanium, hyponitrous acid, maleic anhydride,
nitroalkanes, nitrobenzene, nitrogen trichloride, 2-nitrophenol,
potassium peroxodisulfate, sugars, 2,2,3,3-tetrafluoropropanol,
tetrahydrofuran, thorium dicarbide, 2,4,6-trinitrotoluene
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: May occur.
Section 11 - Toxicological Information
|
RTECS#:
CAS# 109-53-5:
KO1300000
CAS# 1310-58-3:
TT2100000
LD50/LC50:
CAS# 109-53-5:
Oral, rat: LD50 =
17 mL/kg;
Skin, rabbit: LD50 = 20
mL/kg;
.
CAS# 1310-58-3:
Draize test,
rabbit, skin: 50 mg/24H Severe;
Oral, rat: LD50 = 273 mg/kg;
.
Carcinogenicity:
CAS# 109-53-5:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 1310-58-3:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
No data available.
Teratogenicity:
No data available.
Reproductive Effects:
No data available.
Mutagenicity:
Ames-test: non-mutagenic
Neurotoxicity:
No data available.
Other Studies:
Section 12 - Ecological Information
|
Ecotoxicity:
No data available.
No information available.
Environmental:
Biodegradable
Physical:
No information available.
Other:
No information available.
Section 13 - Disposal Considerations
|
Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information
|
|
US DOT |
Canada TDG |
Shipping Name: |
VINYL ISOBUTYL ETHER, STABILIZED |
No information available. |
Hazard Class: |
3 |
|
UN Number: |
UN1304 |
|
Packing Group: |
II |
|
Section 15 - Regulatory Information
|
US FEDERAL
TSCA
CAS# 109-53-5 is listed on the TSCA inventory.
CAS# 1310-58-3 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
CAS# 1310-58-3: 1000 lb final RQ; 454 kg final RQ
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 1310-58-3: immediate, reactive.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
CAS# 1310-58-3 is listed as a Hazardous Substance under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 109-53-5 can be found on the
following state right to know lists: New Jersey, Pennsylvania,
Massachusetts.
CAS# 1310-58-3 can be found on the
following state right to know lists: California, New Jersey,
Pennsylvania, Minnesota, Massachusetts.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
F
Risk Phrases:
R 11 Highly flammable.
Safety Phrases:
S 16 Keep away from sources of ignition - No smoking.
S 33 Take precautionary measures against static discharges.
S 37 Wear suitable gloves.
S 9 Keep container in a well-ventilated place.
WGK (Water Danger/Protection)
CAS# 109-53-5: 1
CAS# 1310-58-3: 1
Canada - DSL/NDSL
CAS# 109-53-5 is listed on Canada's DSL List.
CAS# 1310-58-3 is listed on Canada's DSL List.
Canada - WHMIS
not available.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 1310-58-3 is listed on the Canadian Ingredient Disclosure List.
Section 16 - Additional Information
|
MSDS Creation Date: 9/02/1997
Revision #4 Date: 10/25/2007
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.