Material Safety Data Sheet
Isobutyl vinyl ether, 99.5% (gc), stabilized with 0.1% potassium hydroxide

ACC# 97765
Section 1 - Chemical Product and Company Identification
MSDS Name: Isobutyl vinyl ether, 99.5% (gc), stabilized with 0.1% potassium hydroxide
Catalog Numbers: AC302670000, AC302670010, AC302670050, AC302672500
Synonyms:
1-(Ethenyloxy)-2-methylpropane
Company Identification:

              Acros Organics N.V.
              One Reagent Lane
              Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300

Section 2 - Composition, Information on Ingredients

CAS# Chemical Name Percent EINECS/ELINCS
109-53-5 Isobutyl vinyl ether 99.5 203-678-8
1310-58-3 Potassium hydroxide <1.0 215-181-3

Section 3 - Hazards Identification

EMERGENCY OVERVIEW

Appearance: clear, colorless liquid. Flash Point: -9.4 deg C.
Danger! Extremely flammable liquid and vapor. Vapor may cause flash fire. May cause eye, skin, and respiratory tract irritation. The toxicological properties of this material have not been fully investigated.
Target Organs: None known.


Potential Health Effects
Eye: May cause eye irritation.
Skin: May cause skin irritation.
Ingestion: May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation: May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Vapors may cause dizziness or suffocation.
Chronic: None

Section 4 - First Aid Measures


Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin: Get medical aid if irritation develops or persists. Flush skin with plenty of soap and water.
Ingestion: If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation: Remove from exposure and move to fresh air immediately. Get medical aid if cough or other symptoms appear.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures


General Information: Get medical aid if cough or other symptoms appear. As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors can travel to a source of ignition and flash back. Extremely flammable liquid and vapor. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas.
Extinguishing Media: For small fires, use water spray, dry chemical, carbon dioxide or chemical foam. For large fires, use water spray, fog or alcohol-resistant foam. Do NOT use straight streams of water.
Flash Point: -9.4 deg C ( 15.08 deg F)
Autoignition Temperature: 195 deg C ( 383.00 deg F)
Explosion Limits, Lower:1.40 vol %
Upper: 7.80 vol %
NFPA Rating: (estimated) Health: ; Flammability: ; Instability:

Section 6 - Accidental Release Measures


General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove all sources of ignition.

Section 7 - Handling and Storage


Handling: Wash thoroughly after handling. Use with adequate ventilation. Ground and bond containers when transferring material. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Keep away from heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage: Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - Exposure Controls, Personal Protection


Engineering Controls: Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
Chemical Name ACGIH NIOSH OSHA - Final PELs
Isobutyl vinyl ether none listed none listed none listed
Potassium hydroxide 2 mg/m3 Ceiling none listed none listed

OSHA Vacated PELs: Isobutyl vinyl ether: No OSHA Vacated PELs are listed for this chemical. Potassium hydroxide: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - Physical and Chemical Properties


Physical State: Liquid
Appearance: clear, colorless
Odor: Ether-like
pH: Not available.
Vapor Pressure: 89 mbar @20 deg C
Vapor Density: 3.45
Evaporation Rate:Not available.
Viscosity: 0.476 mPas 5 deg C
Boiling Point: 83 deg C @ 760.00mm Hg
Freezing/Melting Point:-112 deg C
Decomposition Temperature:Not available.
Solubility: 0.7 G/L (25C)
Specific Gravity/Density:.7690g/cm3
Molecular Formula:C6H12O
Molecular Weight:100.0834

Section 10 - Stability and Reactivity


Chemical Stability: Stability unknown.
Conditions to Avoid: Incompatible materials, ignition sources.
Incompatibilities with Other Materials: Isobutyl vinyl ether is incompatible with strong oxidizing agents, and strong acids. Potassium hydroxide is incompatible with acids, amoonia hexachloroplatinate, p-Bis(1,3-dibromoethyl) benzene, bromoform, cyclic polyethylene oxides, chlorine dioxide, cyclopentadiene, germanium, hyponitrous acid, maleic anhydride, nitroalkanes, nitrobenzene, nitrogen trichloride, 2-nitrophenol, potassium peroxodisulfate, sugars, 2,2,3,3-tetrafluoropropanol, tetrahydrofuran, thorium dicarbide, 2,4,6-trinitrotoluene
Hazardous Decomposition Products: Carbon monoxide, carbon dioxide.
Hazardous Polymerization: May occur.

Section 11 - Toxicological Information


RTECS#:      
CAS# 109-53-5: KO1300000      
CAS# 1310-58-3: TT2100000
LD50/LC50:
CAS# 109-53-5:
     Oral, rat: LD50 = 17 mL/kg;
     Skin, rabbit: LD50 = 20 mL/kg;
.

CAS# 1310-58-3:
     Draize test, rabbit, skin: 50 mg/24H Severe;
     Oral, rat: LD50 = 273 mg/kg;
.

Carcinogenicity:
CAS# 109-53-5: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 1310-58-3: Not listed by ACGIH, IARC, NTP, or CA Prop 65.

Epidemiology: No data available.
Teratogenicity: No data available.
Reproductive Effects: No data available.
Mutagenicity: Ames-test: non-mutagenic
Neurotoxicity: No data available.
Other Studies:

Section 12 - Ecological Information


Ecotoxicity: No data available. No information available.
Environmental: Biodegradable
Physical: No information available.
Other: No information available.

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information

US DOT Canada TDG
Shipping Name: VINYL ISOBUTYL ETHER, STABILIZED No information available.
Hazard Class: 3
UN Number: UN1304
Packing Group: II

Section 15 - Regulatory Information

US FEDERAL

TSCA
     CAS# 109-53-5 is listed on the TSCA inventory.
     CAS# 1310-58-3 is listed on the TSCA inventory.
Health & Safety Reporting List
     None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
     None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
     None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
     None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
     CAS# 1310-58-3: 1000 lb final RQ; 454 kg final RQ
SARA Section 302 Extremely Hazardous Substances
     None of the chemicals in this product have a TPQ.
SARA Codes
     CAS # 1310-58-3: immediate, reactive.
Section 313      No chemicals are reportable under Section 313.
Clean Air Act:
     This material does not contain any hazardous air pollutants.
     This material does not contain any Class 1 Ozone depletors.
     This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
CAS# 1310-58-3 is listed as a Hazardous Substance under the CWA.
     None of the chemicals in this product are listed as Priority Pollutants under the CWA.
     None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
     None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
     CAS# 109-53-5 can be found on the following state right to know lists: New Jersey, Pennsylvania, Massachusetts.
     CAS# 1310-58-3 can be found on the following state right to know lists: California, New Jersey, Pennsylvania, Minnesota, Massachusetts.

California Prop 65

California No Significant Risk Level: None of the chemicals in this product are listed.

European/International Regulations

European Labeling in Accordance with EC Directives
Hazard Symbols:
     F
Risk Phrases:

     R 11 Highly flammable.

Safety Phrases:

     S 16 Keep away from sources of ignition - No smoking.
     S 33 Take precautionary measures against static discharges.
     S 37 Wear suitable gloves.
     S 9 Keep container in a well-ventilated place.

WGK (Water Danger/Protection)

     CAS# 109-53-5: 1
     CAS# 1310-58-3: 1
Canada - DSL/NDSL
     CAS# 109-53-5 is listed on Canada's DSL List.
     CAS# 1310-58-3 is listed on Canada's DSL List.
Canada - WHMIS
     not available.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
     CAS# 1310-58-3 is listed on the Canadian Ingredient Disclosure List.

Section 16 - Additional Information

MSDS Creation Date: 9/02/1997
Revision #4 Date: 10/25/2007

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.